HRID5997

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID15809

4-Nitrothiophenol

C6H5NO2S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc([N+](=O)[O-])cc2)SC[C@H]1OC(C)=O

HCID10646240

未命名化合物

收率 79%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID3007857

Zinc oxide

OZn

PROCEDURE

实验过程

If the procedure described in Preparation IV is followed starting from 6 g (38.10-3 mol) of 4-nitrobenzenethiol, 15.1 g (42.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 3.2 g (39.10-3 mol) of zinc oxide (ZnO), 13 g (yield: 79%) of the expected product are obtained after precipitation in ether.