HRID5999

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11591

Mercuric cyanide

C2HgN2

HCID136653

4-(Trifluoromethyl)thiophenol

C7H5F3S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(C(F)(F)F)cc2)SC[C@H]1OC(C)=O

HCID14795341

未命名化合物

收率 40%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 5.58 g (32.10-3 mol) of 4-tri-fluoromethylbenzenethiol, 8.87 g (35.10-3 mol) of mercuric cyanide, Hg(CN)2, and 12.3 g (35.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 6.2 g (yield: 40%) of the expected product are obtained.

WORKUP

后处理

customIf the procedure described in Preparation I