HRID6000

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID136653

4-(Trifluoromethyl)thiophenol

C7H5F3S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(C(F)(F)F)cc2)SC[C@H]1OC(C)=O

HCID14795341

未命名化合物

收率 48%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID3007857

Zinc oxide

OZn

PROCEDURE

实验过程

If the procedure described in Preparation IV is followed starting from 5.6 g (32.10-3 mol) of 4trifluoromethylbenzenethiol, 12.3 g (35.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 2.55 g (32.10-3 mol) of zinc oxide (ZnO), 7.4 g (yield: 48%) of the expected product are obtained after precipitation in ether.