HCID 58085471, compound → HCID 67057479, compound

HRID 600157Notes

Reaction equation

HRID 600157 reaction equation
CC1(C)C(C)(C)OB(C2C=CC([N:15]([C:23]3[CH:28]=[CH:27][C:26](C)=[CH:25][CH:24]=3)[C:16]3[CH:21]=[CH:20][C:19]([CH3:22])=[CH:18][CH:17]=3)=CC=2)O1.Br[C:32]1[CH:33]=[CH:34][C:35]2[C:39](C3C=CC(C)=CC=3)=[C:38](C3C=CC(C)=CC=3)[S:37][C:36]=2[CH:54]=1>>[C:19]1([CH3:22])[CH:20]=[CH:21][C:16]([NH:15][C:24]2[C:23]([NH:15][C:16]3[CH:17]=[CH:18][C:19]([CH3:22])=[CH:20][CH:21]=3)=[CH:28][CH:27]=[CH:26][C:25]=2[C:38]2[S:37][C:36]3[CH:54]=[CH:32][CH:33]=[CH:34][C:35]=3[CH:39]=2)=[CH:17][CH:18]=1

Participants

3

Reactant 2

HCID 58085471HCID 58085471, compoundHCID 58836075HCID 58836075, compound

Product 1

HCID 67057479HCID 67057479, compound

Procedure

2,3-di-p-tolylaminophenyl-benzo[b]thiophene was synthesized in the same manner as in Synthesis Example 1, except that [4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-phenyl]-di-p-tolylamine was used instead of p-tolylboronic acid used to synthesize Intermediate B in Synthesis Example 1.

Workup

  1. customin Synthesis Example 1

Sources & evidence

ORD record
ord-26dcd263ec8e4ec1995c812909e574e2
Source dataset
uspto-grants-2011_03
Patent number
US07901793B2

Reaction notes

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