HRID6003

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

HCID14795334

3-Sulfanylbenzonitrile

C7H5NS

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2cccc(C#N)c2)SC[C@H]1OC(C)=O

HCID14795343

未命名化合物

收率 31%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID3007857

Zinc oxide

OZn

PROCEDURE

实验过程

If the procedure described in Preparation IV is followed starting from 10.3 g (74.1.10-3 mol) of 3-mercaptobenzonitrile, 28.94 g (81.5.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 6.05 g (74.3.10-3 mol) of zinc oxide (ZnO), 9.6 g (yield: 31%) of the expected product are obtained.