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HRID6005

反应详情

EQUATION

反应方程式

HRID 6005 的结构方程式

REACTANTS

反应物

3
结构：N#[C][Hg][C]#N
HCID11591

Mercuric cyanide

C2HgN2

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O
HCID10926314

未命名化合物

结构：N#Cc1ccccc1S
HCID11018926

2-mercaptobenzonitrile

C7H5NS

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccccc2C#N)SC[C@H]1OC(C)=O
HCID14795345

未命名化合物

收率 50%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 9.70 g (72.10-3 mol) of 2-mercaptobenzonitrile, 19.45 g (77.10-3 mol) of mercuric cyanide, Hg(CN)2, and 27.4 g (77.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 14.7 g (yield: 50%) of the expected product are obtained.

WORKUP

后处理

  1. customIf the procedure described in Preparation I