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HRID6007

反应详情

EQUATION

反应方程式

HRID 6007 的结构方程式

REACTANTS

反应物

3
结构：N#[C][Hg][C]#N
HCID11591

Mercuric cyanide

C2HgN2

结构：O=[N+]([O-])c1ccccc1S
HCID21002

o-Nitrobenzenethiol

C6H5NO2S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O
HCID10926314

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccccc2[N+](=O)[O-])SC[C@H]1OC(C)=O
HCID14795347

未命名化合物

收率 48%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 6 g (38.7.10-3 mol) of 2-nitrobenzenethiol, 10.75 g (42.5.10-3 mol) of mercuric cyanide, Hg(CN)2, and 15.12 g (42.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 8 g (yield: 48%) of the expected product are obtained.

WORKUP

后处理

  1. customIf the procedure described in Preparation I