HRID6009

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7969

Benzenethiol

C6H6S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccccc2)SC[C@H]1OC(C)=O

HCID14795349

未命名化合物

收率 52.3%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 4 g (36.3.10-3 mol) of benzenethiol, 14 g (39.4.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-xylopyranosyl bromide and 10 g (39.10-3 mol) of mercuric cyanide (Hg(CN)2), 7.3 g of the expected product are obtained after crystallization from ether.

WORKUP

后处理

customIf the procedure described in Preparation I