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HRID6012

反应详情

EQUATION

反应方程式

HRID 6012 的结构方程式

REACTANTS

反应物

3
结构：N#[C][Hg][C]#N
HCID11591

Mercuric cyanide

C2HgN2

结构：O=[N+]([O-])c1cccc(S)c1
HCID243576

3-nitrobenzenethiol

C6H5NO2S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O
HCID10926314

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2cccc([N+](=O)[O-])c2)SC[C@H]1OC(C)=O
HCID14795355

未命名化合物

收率 27%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 10 g (64.5.10-3 mol) of 3-nitrobenzenethiol, 16.29 g (64.5.10-3 mol) of mercuric cyanide (Hg(CN)2) and 25.2 g (70.9.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 7.44 g (yield: 27%) of the expected product are obtained after purification by flash chromatography using a toluene/ethyl acetate mixture (9/1 v/v) as the eluent, followed by crystallization from ether.

WORKUP

后处理

  1. customIf the procedure described in Preparation I