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HRID6014

反应详情

EQUATION

反应方程式

HRID 6014 的结构方程式

REACTANTS

反应物

3
结构：N#[C][Hg][C]#N
HCID11591

Mercuric cyanide

C2HgN2

结构：FC(F)(F)c1ccccc1S
HCID2777889

2-(Trifluoromethyl)benzenethiol

C7H5F3S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O
HCID10926314

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccccc2C(F)(F)F)SC[C@H]1OC(C)=O
HCID14795357

未命名化合物

收率 34%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 1.8 g (10.10-3 mol) of 2trifluoromethylbenzenethiol, 2.55 g (10.10-3 mol) of mercuric cyanide (Hg(CN)2) and 3.95 g (11.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 1.53 g (yield: 34%) of the expected product are obtained.

WORKUP

后处理

  1. customIf the procedure described in Preparation I