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HRID6016

反应详情

EQUATION

反应方程式

HRID 6016 的结构方程式

REACTANTS

反应物

3
结构：N#[C][Hg][C]#N
HCID11591

Mercuric cyanide

C2HgN2

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O
HCID10926314

未命名化合物

结构：N#Cc1ccc(-c2ccc(S)cc2)cc1
HCID14795335

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(-c3ccc(C#N)cc3)cc2)SC[C@H]1OC(C)=O
HCID14795359

未命名化合物

收率 10.2%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 2.3 g (10.9.10-3 mol) of 4-(4-mercaptophenyl)benzonitrile, 4.26 g (11.9.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 2.75 g (10.9.10-3 mol) of mercuric cyanide (Hg(CN)2), 0.540 g (yield: 10%) of the expected product is obtained after purification by flash chromatography using methylene chloride as the eluent.

WORKUP

后处理

  1. customIf the procedure described in Preparation I