HRID6018

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11591

Mercuric cyanide

C2HgN2

2 次

HCID518690

3,5-Bis(trifluoromethyl)benzenethiol

C8H4F6S

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2cc(C(F)(F)F)cc(C(F)(F)F)c2)SC[C@H]1OC(C)=O

HCID14795361

未命名化合物

收率 35.7%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 1.6 g (6.5.10-3 mol) of 3,5-bis(trifluoromethyl)benzenethiol, 1.64 g (6.5.10-3 mol) of mercuric cyanide, Hg(CN)2, and 2.54 g (7.5.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 1.2 g (yield: 35.7%) of the expected product are obtained. M.p.=201° C.

WORKUP

后处理

customIf the procedure described in Preparation I