3-TETRAHYDROPYRANYLOXY-1-TRIMETHYLSILYL-1-PROPYNE → HCID 59180087, compound

HRID 601946Notes

Reaction equation

HRID 601946 reaction equation
[CH3:1][Si:2]([CH3:14])([CH3:13])[C:3]#[C:4][CH2:5][O:6][CH:7]1[CH2:12][CH2:11][CH2:10][CH2:9][O:8]1.Br[CH2:16]/[CH:17]=[CH:18]\[CH2:19][CH2:20][CH3:21]>>[CH3:14][Si:2]([CH3:13])([CH3:1])[C:3]#[C:4][CH:5]([O:6][CH:7]1[CH2:12][CH2:11][CH2:10][CH2:9][O:8]1)[CH2:16]/[CH:17]=[CH:18]\[CH2:19][CH2:20][CH3:21]

Participants

3

Reactant 2

HCID 107037813-TETRAHYDROPYRANYLOXY-1-TRIMETHYLSILYL-1-PROPYNEHCID 10997371HCID 10997371, compound

Product 1

HCID 59180087HCID 59180087, compound

Procedure

Reaction of trimethyl(3-(tetrahydro-2H-pyran-2-yloxy)prop-1-ynyl)silane and (Z)-1-bromohex-2-ene according to General Procedure 11.A provided (Z)-trimethyl(3-(tetrahydro-2H-pyran-2-yloxy)non-5-en-1-ynyl)silane.

Sources & evidence

ORD record
ord-452fb43326dc4acea660b6d6e90f335b
Source dataset
uspto-grants-2011_03
Patent number
US07902252B2

Reaction notes

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