HRID6020

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11591

Mercuric cyanide

C2HgN2

2 次

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](Br)SC[C@H]1OC(C)=O

HCID10926314

未命名化合物

HCID14795336

4-Sulfanylbenzene-1,3-dicarbonitrile

C8H4N2S

PRODUCTS

生成物

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(C#N)cc2C#N)SC[C@H]1OC(C)=O

HCID14795363

未命名化合物

收率 40.5%

PROCEDURE

实验过程

If the procedure described in Preparation I is followed starting from 1.5 g (9.10-3 mol) of 3-cyano-4-mercaptobenzonitrile, 2.78 g (11.10-3 mol) of mercuric cyanide, Hg(CN)2, and 3.66 g (11.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 1.65 g (yield: 40.5%) of the expected product are obtained.

WORKUP

后处理

customIf the procedure described in Preparation I