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HRID6022

反应详情

EQUATION

反应方程式

HRID 6022 的结构方程式

REACTANTS

反应物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(C#N)cc2C#N)SC[C@H]1OC(C)=O
HCID14795363

未命名化合物

PRODUCTS

生成物

1
结构：N#Cc1ccc(S[C@@H]2SC[C@@H](O)[C@H](O)[C@H]2O)c(C#N)c1
HCID14795395

未命名化合物

收率 67%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO.ClCCl
溶剂HCID21226129

未命名化合物

PROCEDURE

实验过程

If the procedure described in Preparation V is followed, except that the reaction is carried out at 0° C., starting from 1.5 g (34.10-3 mol) of 2,4-dicyanophenyl 2,3,4-tri-O-acetyl-1,5-dithio-β-D-xylopyranoside (Example 16a), 0.71 g (yield: 67%) of the expected product is obtained after chromatography on silica using a CH2Cl2 /CH3OH mixture (8/1 v/v) as the eluent.

WORKUP

后处理

  1. customIf the procedure described in Preparation V
  2. customis carried out at 0° C.