HRID6026

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70777

4'-Mercaptoacetanilide

C8H9NOS

结构：CC(=O)O[C@H]1[C@H](OC(C)=O)CSC(Br)[C@@H]1OC(C)=O

HCID11382683

未命名化合物

PRODUCTS

生成物

结构：CC(=O)Nc1ccc(S[C@@H]2SC[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]2OC(C)=O)cc1

HCID53835491

未命名化合物

收率 25%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID3007857

Zinc oxide

OZn

PROCEDURE

实验过程

If the procedure described in Preparation IV is followed starting from 4.5 g (27.10-3 mol) of N-(4-mercaptophenyl)acetamide, 11.43 g (32.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-D-xylopyranosyl bromide and 2.16 g (27.10-3 mol) of zinc oxide (ZnO), 3 g (yield: 25%) of the expected product are obtained after recrystallization from a toluene/isopropyl ether mixture.