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HRID6038

反应详情

EQUATION

反应方程式

HRID 6038 的结构方程式

REACTANTS

反应物

2
结构：C[O-].[Na+]
HCID10942334

Methanol, sodium salt

CH3NaO

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)CS[C@H]1Oc1ccc(C(C)=O)cc1
HCID15067850

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)c1ccc(O[C@@H]2SC[C@@H](O)[C@H](O)[C@H]2O)cc1
HCID15067851

未命名化合物

收率 88.2%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

If the procedure described in Preparation LXXXIV is followed starting from 0.9 g (2.2.10-3 mol) of 4-acetylphenyl 2,3,4-tri-O-acetyl-5-thio-β-D-xylopyranoside and 0.8 ml of a solution of sodium methylate in methanol (8% w/v of Na), reacted in 50 ml of methanol for 1 h, 0.55 g (yield: 88%) of the expected product is obtained after lyophilization.

WORKUP

后处理

  1. customIf the procedure described in Preparation LXXXIV