HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Methoxide → 2-cyanophenyl 5-thio-beta-D-xylopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Reactant | 2-cyanophenyl 2,3,4-tri-O-acetyl-5-thio-beta-D-xylopyranoside | HCID 15067854 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 2-cyanophenyl 5-thio-beta-D-xylopyranoside | HCID 15067855 | 88% |
Reaction Steps
If the procedure described in Preparation LXXXIV is followed starting from 1.26 g (3.2.10-3 mol) of 2-cyanophenyl 2,3,4-tri-O-acetyl-5-thio-β-D-xylopyranoside and 0.2 ml of a solution of sodium methylate in methanol (8% w/v of Na), reacted in 70 ml of methanol for 30 min, 0.75 g (yield: 88%) of the expected product is obtained after precipitation in ether and lyophilization.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05246961 |
| Source dataset | uspto-grants-1993_09 |
| ORD ID | ord-77ee1249bab045feb3c459539c7d4d4c |
| Source note | uspto-grants-1993_09 |