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HRID6047

反应详情

EQUATION

反应方程式

HRID 6047 的结构方程式

REACTANTS

反应物

2
结构：C[O-].[Na+]
HCID10942334

Methanol, sodium salt

CH3NaO

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)CS[C@H]1Oc1ccccc1[N+](=O)[O-]
HCID15067858

未命名化合物

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccccc1O[C@@H]1SC[C@@H](O)[C@H](O)[C@H]1O
HCID15067859

未命名化合物

收率 68%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

If the procedure described in Preparation LXXXIV is followed starting from 0.85 g (2.05.10-3 mol) of 2-nitrophenyl 2,3,4-tri-O-acetyl-5-thio-β-D-xylopyranoside and 0.1 ml of a solution of sodium methylate in methanol (8% w/v of Na), reacted in 50 ml of methanol for 30 min, 0.4 g (yield: 68%) of the expected product is obtained after precipitation in ether and lyophilization.

WORKUP

后处理

  1. customIf the procedure described in Preparation LXXXIV