Acetic Acid → HCID 67040433, compound

Participants

Reaction Conditions

Reaction Steps

The product from Example 384C (0.20 gm, 0.30 mmol) was suspended in a 4/1 v-v mixture of glacial acetic acid and ethanol (8 ml). To this vigorously stirred suspension was added, in one portion, iron powder (0.215 gm, 3.85 mmol) and the resulting mixture heated under nitrogen in an oil bath at 100° C. After 19.5 hours the reaction mixture was cooled then concentrated under vacuum to a paste which was suspended in water and the solid product collected by vacuum filtration. The cake was washed with water then dried in vacuo at room temperature (0.204 gm, quant.).

Provenance & Evidence