5-Methyl-2-(1-methyl-1H-pyrazol-4-yl)benzoic acid → 5-Methyl-2-(1-methyl-1H-pyrazol-3-yl)benzoic acid

HRID 60918Notes

Reaction equation

HRID 60918 reaction equation
CC1C=CC(C2C=NN(C)C=2)=C(C=1)C(O)=O.[CH3:17][C:18]1[CH:19]=[CH:20][C:21]([C:28]2[CH:32]=[CH:31][N:30]([CH3:33])[N:29]=2)=[C:22]([CH:27]=1)[C:23]([O:25]C)=[O:24]>>[CH3:17][C:18]1[CH:19]=[CH:20][C:21]([C:28]2[CH:32]=[CH:31][N:30]([CH3:33])[N:29]=2)=[C:22]([CH:27]=1)[C:23]([OH:25])=[O:24]

Participants

3

Reactant 2

HCID 811115005-Methyl-2-(1-methyl-1H-pyrazol-4-yl)benzoic acidHCID 117727908Methyl 5-methyl-2-(1-methyl-1H-pyrazol-3-yl)benzoate

Product 1

HCID 1031315225-Methyl-2-(1-methyl-1H-pyrazol-3-yl)benzoic acid

Procedure

The title compound was synthesized following the same general protocol as described for 5-methyl-2-(1-methyl-1H-pyrazol-4-yl)benzoic acid in Example A1, using methyl 5-methyl-2-(1-methyl-1H-pyrazol-3-yl)benzoate. ESI-MS (m/z): 217 [M+1]+.

Sources & evidence

ORD record
ord-67855b517a70445c9dbc560a4f6e1e32
Source dataset
uspto-grants-2016_09
Patent number
US09440982B2

Reaction notes

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