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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 609511Generated: October 31, 2026

Citric Acid → 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, manganese(3+) salt (1:1)

https://huagongshe.com/reaction/609511

Reaction equation

Participants

RoleNameHCIDCharge
ReactantCitric AcidHCID 311—
ReactantManganeseHCID 23930—
ReactantManganese oxideHCID 160959—
SolventWaterHCID 962—
Product1,2,3-Propanetricarboxylic acid, 2-hydroxy-, manganese(3+) salt (1:1)HCID 22274—

Reaction Steps

A fertilizer additive containing 5% manganese was prepared by adding 360 grams of citric acid to 1181 grams of water. After the citric acid was dissolved, 128 grams of manganese (II) oxide was added to the mix and allowed to react and form manganese citrate, an insoluble white to very light pink precipitate. After the precipitate formed, 320 grams of 2-hydroxyethylamine and 10 grams of dimethylaminopropylamine were added. The precipitate was dissolved to produce a clear 5% manganese chelated solution having a pH of 10.8. This additive was added to conventional, N--P--K liquid fertilizers to produce clear fertilizer compositions.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05997600
Source datasetuspto-grants-1999_12
ORD IDord-1d96800f2dc44924b95b5b38c02cd91c
Source noteuspto-grants-1999_12