Ethanethiol → HCID 22393124, compound

Participants

Reaction Steps

The compound of Example 26 (1.05 g, 2.71 mmol) was treated with aluminum bromide and ethanethiol according to the procedure for Example 18 giving the title product (0.90 g, 89%). 1H NMR (DMSO-d6) δ 9.99 (s, 1H); 7.27-6.74 (m, 8H); 3.61 (br s, 2H), 3.20 (s, 2H); 1.50-1.00 (m, 8H); 0.73 (m, 6H). MS Da/e=374 (MH+). Calcd for C21H27NSO3 ×0.25 H2O: C, 66.73; H, 7.33, N, 3.71, S, 8.48. Found: C, 66.67; H, 7.32; N, 3.67; S, 8.49.

Provenance & Evidence