化工社化工社 化学情報印刷レポート · 研究参考用
Acetic Acid → Methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Ethanol | HCID 702 | — |
| 反応物 | 6-Methoxy-2-methyl-2,3-dihydro-1H-inden-1-one | HCID 231178 | — |
| 反応物 | 2-Methyl-6-nitro-1-indanone | HCID 21840586 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate | HCID 53908697 | — |
反応手順
The procedure of Example 13C is followed using 2-methyl-6-nitro indanone in equivalent quantities in place of 6-methyoxy-2-methyl-indanone used therein. After the mixture is condensed, 30 ml of ethanol and 50 ml of acetic acid are added. The mixture is then poured into 700 ml of water. Extraction with ether gives methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05998477 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-c062fcd008344d1eaa6c41effc264755 |
| 出典メモ | uspto-grants-1999_12 |