HCID 21266598, compound → HCID 21266606, compound

HRID 610616Notes

Reaction equation

HRID 610616 reaction equation
C1(C)C=CC=CC=1C(C1C=CC=CC=1C)CCCI.[C:20]1([CH3:38])[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[C:26]([C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][C:32]=1[CH3:37])=[CH:27][CH2:28][CH2:29][NH2:30]>>[C:20]1([CH3:38])[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[CH:26]([C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][C:32]=1[CH3:37])[CH2:27][CH2:28][CH2:29][NH2:30]

Participants

3

Reactant 2

HCID 21266598HCID 21266598, compoundHCID 21266613HCID 21266613, compound

Product 1

HCID 21266606HCID 21266606, compound

Procedure

Prepared via the 4,4-di-(2-tolyl)-1-butyliodide, 33a and isolated as an oil. 1H NMR (CDCl3) δ1.20 (s broad, 2H), 1.42-1.58 (m,2H), 1.87-2.03 (m,2H), 2.27 (s,6H), 2.70 (t,2H), 4.23 (t,1H), 7.05-7.16 (m,8H) 4,4-Di-(2-tolyl)-3-butenylamine, 30c. Prepared via the 4,4-di-(2-tolyl)-3-butenylodide 36a and isolated as an oil. 1H NMR (CDCl3) δ1.20 (s broad, 2H), 2.11 (s,3H), 2.18 (q,2H), 2.26 (s,3H), 2.77 (t,2H), 5.75 (t,1H), 7.02-7.18 (m,8H).

Workup

  1. customisolated as an oil
  2. customisolated as an oil

Sources & evidence

ORD record
ord-7c9189450a35483e91ee7c31a66b13bf
Source dataset
uspto-grants-1999_12
Patent number
US05998613

Reaction notes

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