Acetylene → HCID 19601757, compound

HRID 610717Notes

Reaction equation

HRID 610717 reaction equation
[CH:1]#[CH:2].[Cl:3][SiH:4]([CH:6]([SiH:11]([Cl:13])[Cl:12])[Si:7]([Cl:10])([Cl:9])[Cl:8])[Cl:5]>C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC=CC=1>[Cl:5][Si:4]1([Cl:3])[CH:2]=[CH:1][Si:11]([Cl:12])([Cl:13])[CH:6]1[Si:7]([Cl:8])([Cl:10])[Cl:9]

Participants

5

Reactant 2

HCID 6326Acetylene2×HCID 102356231HCID 102356231, compound2×

Product 1

HCID 19601757HCID 19601757, compoundYield 50.3%

Reagents, catalysts & solvents 2

HCID 178418397HCID 178418397, compoundCatalyst2×HCID 241BenzeneSolvent

Procedure

Hydrosilation of acetylene with bis(dichlorosilyl)trichlorosilylmethane in the presence of Pd(PPh3)4. Into the same apparatus as described in Example 1 were added 1.01 g of bis(dichlorosilyl)trichlorosilylmethane, 0.103 g of Pd(PPh3)4, and 25 ml of dried benzene to form a mixture. Acetylene gas was blown into the mixture at a rate of 90 ml per minute for 3 hours. The resulting mixture was vacuum distilled at 67 Pa to yield a mixture comprising 0.89 g of 1,1,3,3-tetrachloro-2-trichlorosilyl-1,3-disilacyclopent-4-ene (TCD-GC area 50.3%).

Workup

  1. customto form a mixture
  2. distillationdistilled at 67 Pa

Sources & evidence

ORD record
ord-6ee81992010648709fd514c4a1f20b93
Source dataset
uspto-grants-1999_12
Patent number
US05998649

Reaction notes

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