Formic Acid → Terephthalic acid copper

HRID 610736Notes

Reaction equation

HRID 610736 reaction equation
[C:1]([OH:12])(=[O:11])[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1.C(O)=O.C([O-])(=O)C.[Cu+2:20].C([O-])(=O)C>CO>[Cu:20].[C:1]([OH:12])(=[O:11])[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 284Formic AcidHCID 7489Terephthalic AcidHCID 8895Cupric acetate

Product 1

HCID 66870991Terephthalic acid copperYield 67%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

0.41 g of terephthalic acid was dissolved under heating in a mixture solvent of 250 cm3 of methanol and 15 cm3 of formic acid. After this solution was cooled to the normal temperature, into this solution, a further solution in which 0.50 g of copper acetate was dissolved in 40 cm3 of methanol was dripped and then this was kept still for a few days. Thereafter, the precipitation product was suction-filtered and dried for 110° C./4 hours, whereby 0.38 g of terephthalic acid copper was obtained.

Workup

  1. temperatureAfter this solution was cooled to the normal temperature, into this solution
  2. waitthis was kept still for a few days
  3. filtrationThereafter, the precipitation product was suction-filtered
  4. customdried for 110° C./4 hours

Sources & evidence

ORD record
ord-1e61d02bd9cb40a6bee0244dd41bb339
Source dataset
uspto-grants-1999_12
Patent number
US05998647

Reaction notes

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