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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 610740Generated: October 26, 2026

Formic Acid → (E)-but-2-enedioic acid;copper

https://huagongshe.com/reaction/610740

Reaction equation

Participants

RoleNameHCIDCharge
ReactantFormic AcidHCID 284—
ReactantCupric acetateHCID 8895—
ReactantFumaric AcidHCID 444972—
SolventMethanolHCID 887—
Product(E)-but-2-enedioic acid;copperHCID 9047154533.4%

Reaction Steps

0.58 g of fumaric acid was dissolved in a mixture solvent having 40 cm3 of methanol and 12 cm3 of formic acid. Then, under stirring at the normal temperature, into the above solution, a further solution in which 1.0 g of copper acetate was dissolved in 80 cm3 of methanol was dripped. After this solution was left still for a few days, the precipitation product was suction-filtered and dried for 110° C./4 hours, whereby 0.3 g of fumaric acid copper was obtained.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05998647
Source datasetuspto-grants-1999_12
ORD IDord-7bfb547bc0e74251bb8863eeadb38287
Source noteuspto-grants-1999_12