Terephthalic Acid → Terephthalic acid molybdenum

HRID 610743Notes

Reaction equation

HRID 610743 reaction equation
[C:1]([OH:12])(=[O:11])[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1.C([O-])(=O)C.[Mo+4:17].C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C>CO>[Mo:17].[C:1]([OH:12])(=[O:11])[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 7489Terephthalic AcidHCID 11473018Molybdenum acetate

Product 1

HCID 88024228Terephthalic acid molybdenum

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.854 g (5.14 mmol) of terephthalic acid and 1,000 g (2.34 mmol) of molybdenum acetate were dissolved in 900 ml of methanol. After this was stirred for three days at the room temperature, this was kept still for a few days. Thereafter, its precipitation product was suction-filtered, rinsed sufficiently with methanol and then vacuum-dried for 60° C./4 hours, whereby 1.387 g of target substance was obtained. This substance had the specific surface area of 519 m2 /g. And, a measurement according to the HK method using argon revealed that the substance had the pore diameter of 5.7 Å.

Workup

  1. waitthis was kept still for a few days
  2. customThereafter, its precipitation product
  3. filtrationwas suction-filtered
  4. washrinsed sufficiently with methanol
  5. customvacuum-dried for 60° C./4 hours, whereby 1.387 g of target substance
  6. customwas obtained

Sources & evidence

ORD record
ord-6e4e1df6a863451f8c5b9a9ef6cbea78
Source dataset
uspto-grants-1999_12
Patent number
US05998647

Reaction notes

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