HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylbenzothiazole → 3-Heptyl-2-methylbenzothiazolium iodide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylbenzothiazole | HCID 8446 | — |
| Reactant | 1-Iodoheptane | HCID 20274 | — |
| Product | 3-Heptyl-2-methylbenzothiazolium iodide | HCID 67572016 | — |
Reaction Steps
A solution of 2-methylbenzothiazole (10.0 g, 0.067 mol) and 1-iodoheptane (110 mL, 0.67 mol) in 100 mL of acetronitrile was refluxed under nitrogen for 48 hours. The mixture was cooled, filtered, and the solid formed was washed with diethyl ether and recrystallized from ethanol-ethyl acetate to give 3-heptyl-2-methylbenzothiazolium iodide as a light purple solid, mp 110-113° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06001331 |
| Source dataset | uspto-grants-1999_12 |
| ORD ID | ord-7ef6d825ff6b47c2bd8b1433ab51f5e9 |
| Source note | uspto-grants-1999_12 |