HRID612336

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(C)[Si](C)(C)Oc1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1.[Br-]

HCID10393091

未命名化合物

HCID19593819

未命名化合物

结构：COCCCCC[Si]1(c2ccccc2)CCC(C2CCC(C=O)CC2)CC1

HCID54050763

未命名化合物

PRODUCTS

生成物

结构：COCCCCC[Si@H]1CC[C@H]([C@H]2CC[C@H](CCc3ccc(OCC(F)(F)C(C)(F)F)cc3)CC2)CC1

HCID178495001

未命名化合物

PROCEDURE

实验过程

The general procedure of Example 38 was repeated using 4-(t-butyldimethylsiloxy)benzyltriphenylphosphonium bromide, 4-(4-(5-methoxy-n-pentyl)-4-phenyl-4-silacyclohexyl)cyclohexane carbaldehyde and 1-bromo-2,2,3,3-tetrafluoro-n-butane, thereby obtaining the intended compound.

WORKUP

后处理

customobtaining the intended compound

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-69449da162494eb8a78225541d83bc53
来源数据集: uspto-grants-1999_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06004478
来源说明: uspto-grants-1999_12

反应 SMILES

[Br-].[O:2]([C:10]1[CH:35]=[CH:34][C:13]([CH2:14][P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[CH:12][CH:11]=1)[Si](C(C)(C)C)(C)C.[CH3:36][O:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][Si:43]1(C2C=CC=CC=2)[CH2:48][CH2:47][CH:46]([CH:49]2[CH2:54][CH2:53][CH:52]([CH:55]=O)[CH2:51][CH2:50]2)[CH2:45][CH2:44]1.Br[CH2:64][C:65]([F:71])([F:70])[C:66]([F:69])([F:68])[CH3:67]>>[F:68][C:66]([F:69])([C:65]([F:71])([F:70])[CH3:64])[CH2:67][O:2][C:10]1[CH:11]=[CH:12][C:13]([CH2:14][CH2:55][C@H:52]2[CH2:53][CH2:54][C@H:49]([C@H:46]3[CH2:45][CH2:44][Si@H:43]([CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][O:37][CH3:36])[CH2:48][CH2:47]3)[CH2:50][CH2:51]2)=[CH:34][CH:35]=1