HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester → Dimethyl 4-(4-methylphenoxy)phthalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester | HCID 69119 | — |
| Reactant | Sodium p-methylphenolate | HCID 23673456 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Dimethyl 4-(4-methylphenoxy)phthalate | HCID 19595679 | — |
Reaction Steps
Dimethyl 4-nitrophthalate was reacted in DMF with sodium 4-methylphenoxide to give dimethyl 4-(4-methylphenoxy)phthalate in analogy to a process known from the literature (J. Org. Chem. Vol. 42, No. 21, 1977, 3419-3425). After standard working up and chromatography using hexane/EA, the diester was isolated as a yellowish oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06005010 |
| Source dataset | uspto-grants-1999_12 |
| ORD ID | ord-f90c1636df7f4585930f4d42652aa76d |
| Source note | uspto-grants-1999_12 |