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Dimethylformamide → Dimethyl 4-phenoxyphthalate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | Phenolate Sodium | HCID 4445035 | — |
| 反応物 | HCID 19595681 | HCID 19595681 | — |
| 生成物 | Dimethyl 4-phenoxyphthalate | HCID 19595677 | — |
反応手順
Methyl 4-nitrophthalate was reacted in DMF with sodium phenoxide to give dimethyl 4-phenoxyphthalate in analogy to a process known from the literature (J. Org. Chem. Vol. 42, No. 21, 1977, 3419-3425). After standard working up and chromatography using hexane/EA, the diester was isolated as a yellowish oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06005010 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-fa7b70037ada4929a77540160665e705 |
| 出典メモ | uspto-grants-1999_12 |