Sodium Hydroxide → HCID 21329758, compound

HRID 613975Notes

Reaction equation

HRID 613975 reaction equation
[C:1]1([N:7]=[N:8][C:9]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[N:10][NH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[Na+].[Cl:26]Cl>C(O)C>[ClH:26].[Cl-:26].[C:1]1([N:7]2[N:11]([C:12]3[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=3)[N:10]=[C:9]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)[NH2+:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 24526ChlorineHCID 682741,3,5-Triphenylformazan

Product 1

HCID 21329758HCID 21329758, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

5 g (0.015 M) of 1,3,5-triphenylformazan and 0.7 g (0.015 M) of sodium hydroxide were mixed in 100 ml of absolute ethyl alcohol and 0.96 liter (0.042 M) of chlorine gas was passed through for 45 minutes at a temperature of 05° C. Activated carbon was added, the components mixed, the mixture passed through a filter, the filtrate evaporated, the residue dissolved in water, treated with activated carbon, filtered, and the filtrate evaporated. The obtained crystals were white with a creamy tint. The yield of the end produce was 4.8 g (85 percent).

Workup

  1. customwas passed through for 45 minutes at a temperature of 05° C
  2. additionActivated carbon was added
  3. additionthe components mixed
  4. customthe filtrate evaporated
  5. dissolutionthe residue dissolved in water
  6. additiontreated with activated carbon
  7. filtrationfiltered
  8. customthe filtrate evaporated
  9. customThe yield of the end produce

Sources & evidence

ORD record
ord-97f7d2d8ce3e41a3b242a5cad84ea91b
Source dataset
uspto-grants-1979_03
Patent number
US04143049

Reaction notes

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