HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl Mercaptan → HCID 21328022, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl Mercaptan | HCID 13367 | — |
| Reactant | 5-Chloro-2-nitroaniline | HCID 74218 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 21328022 | HCID 21328022 | 53.9% |
Reaction Steps
To a solution of 7 g of 2-nitro-5-chloroaniline in 200 ml of absolute ethanol there is added 4.2 g of allyl mercaptan and 2.5 g of Na-methoxide. Then the mixture is refluxed for three hours, the solvent is evaporated and the residue is chromatographed on neutral alumina (Activity IV). Elution with ether-petroleum ether yields 4.6 g of 2-nitro-5(2-propenylthio)aniline.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04145431 |
| Source dataset | uspto-grants-1979_03 |
| ORD ID | ord-730f1efb95014f3f9104d3099ce15eab |
| Source note | uspto-grants-1979_03 |