化工社化工社 化学情報印刷レポート · 研究参考用
2-(Chloromethyl)-1-methoxy-4-nitrobenzene → N-methyl-N-(5-nitro-2-methoxybenzyl)N,N-bis(3-formamidopropyl)ammonium chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-(Chloromethyl)-1-methoxy-4-nitrobenzene | HCID 2529377 | — |
| 反応物 | Formamide, N,N'-[(methylimino)di-3,1-propanediyl]bis- | HCID 3084810 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N-methyl-N-(5-nitro-2-methoxybenzyl)N,N-bis(3-formamidopropyl)ammonium chloride | HCID 20336842 | — |
反応手順
Proceeding in a manner similar to that described above in B-8a, 142 parts of N,N-bis(3-formamidopropyl)methylamine and 141 parts of 5-nitro-2-methoxybenzyl chloride were interacted in 115 parts of water to obtain N-methyl-N-(5-nitro-2-methoxybenzyl)N,N-bis(3-formamidopropyl)ammonium chloride. The product was not isolated but was used directly in solution for reduction of the nitro group.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04146558 |
| 出典データセット | uspto-grants-1979_03 |
| ORD ID | ord-7e0765f3da25421a984c210ca7b4dcf8 |
| 出典メモ | uspto-grants-1979_03 |