HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 615861Generated: November 2, 2026
Germanium chloride → Germane, butyltrichloro-
https://huagongshe.com/reaction/615861
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Germanium chloride | HCID 66226 | — |
| Reactant | HCID 178448182 | HCID 178448182 | — |
| Reactant | HCID 178448183 | HCID 178448183 | — |
| Product | Germane, butyltrichloro- | HCID 78586 | — |
| Product | HCID 178448183 | HCID 178448183 | — |
Reaction Steps
Chloropentabutyldigermane having formula 4 of the formula sheet. A mixture of 5.8 g (27.0 mmoles) of germanium tetrachloride and 12.2 g (27.0 mmoles) of hexabutyldigermane was heated for 6.5 hours at 200° C. in a Carius tube. Fractionated distillation yielded 6.0 g of butyltrichlorogermane and 11.2 g of chloropentabutyldigermane; boiling point 130°-131° C./0.06 mm Hg; nD20 =1.4932.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04501702 |
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| Source dataset | uspto-grants-1985_02 |
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| ORD ID | ord-57cf3eb3714b4183851211740e74d692 |
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| Source note | uspto-grants-1985_02 |
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