Carbon Tetrachloride → HCID 20370404, compound

HRID 615984Notes

Reaction equation

HRID 615984 reaction equation
[CH3:1][N:2]([CH3:19])[C:3](=[O:18])[CH:4]([CH3:17])[N:5]1[C:9](C)=C[C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[N:6]1.FO[C:22]([F:25])(F)F.BrBr.[C:28](Cl)(Cl)(Cl)Cl>C(O)(=O)C>[F:25][C:22]1[C:7]([C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=2)=[N:6][N:5]([C:4]([CH3:17])([CH3:28])[C:3]([N:2]([CH3:1])[CH3:19])=[O:18])[CH:9]=1

Participants

6

Reactant 4

HCID 5943Carbon TetrachlorideHCID 24408BromineHCID 78989Hypofluorous acid, trifluoromethyl esterHCID 20370380N,N-Dimethyl-2-(5-methyl-3-phenyl-1H-pyrazol-1-yl)propanamide

Product 1

HCID 20370404HCID 20370404, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Following the procedure of Example 108, but substituting N,N,α,α,-tetramethyl-3-phenylpyrazole-1-acetamide for N,N,α,5-tetramethyl-3-phenylpyrazole-1-acetamide, trifluoromethyl hypofluorite for bromine, and carbon tetrachloride for acetic acid as the reaction solvent there was obtained 4-fluoro-N,N,α,α-tetramethyl-3-phenylpyrazole-1-acetamide.

Sources & evidence

ORD record
ord-efa11989eba448f2a57f5d8e8baa4aa6
Source dataset
uspto-grants-1978_02
Patent number
US04072498

Reaction notes

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