HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzenamine, 4-(methylsulfonyl)-2-nitro- → 4-(methylsulfonyl)benzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzenamine, 4-(methylsulfonyl)-2-nitro- | HCID 89024 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 4-(methylsulfonyl)benzene-1,2-diamine | HCID 6951418 | — |
Reaction Steps
2 G. of 1-amino-4-methylsulfonyl-2-nitrobenzene is treated in 200 ml. methanol with hydrogen at 4 atmospheres pressure in the presence of Raney nickel catalyst. The catalyst is removed by filtration and the filtrate concentrated to yield pure 1,2-diamino-4-methylsulfonylbenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04072696 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-9ee52dbe9eed40f79f831934bd2da0e0 |
| Source note | uspto-grants-1978_02 |