HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Amino-3-nitrophenyl thiocyanate → 1-(3-Methoxycarbonyl-2-thioureido)-2-nitro-4-thiocyanatobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Amino-3-nitrophenyl thiocyanate | HCID 104677 | — |
| Reactant | Methoxycarbonyl isothiocyanate | HCID 552246 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 1-(3-Methoxycarbonyl-2-thioureido)-2-nitro-4-thiocyanatobenzene | HCID 20371075 | — |
Reaction Steps
2.0 G. of 1-amino-2-nitro-4-thiocyanatobenzene in 20 ml. acetone is treated with 3.0 g. methoxycarbonyl isothiocyanate at room temperature for 9 days. The solution is concentrated and the residue triturated with methanol and recrystallized from acetone, yielding 1-(3-methoxycarbonyl-2-thioureido)- 2-nitro-4-thiocyanatobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04072696 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-5b12b509635948e0ad99edc16eebb117 |
| Source note | uspto-grants-1978_02 |