HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 4-[(Methoxymethyl)sulfanyl]benzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 4-[(Methoxymethyl)sulfanyl]-2-nitroaniline | HCID 20362817 | — |
| Catalyst | Iron | HCID 23925 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-[(Methoxymethyl)sulfanyl]benzene-1,2-diamine | HCID 20362832 | — |
Reaction Steps
1.2 G. 1-amino-2-nitro-4-methoxymethylthiobenzene is reduced in 80 ml. methanol and 20 ml. water at reflux with 2.4 g. iron powder and 0.6 g. ferrous sulfate. The mixture is filtered and concentrated. The residue is recrystallized from cyclohexane, yielding pure 1,2-diamino-4-methoxymethylthiobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04072696 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-c14274f2744446d5bfb798a4aff5d855 |
| Source note | uspto-grants-1978_02 |