HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → 4-(Butylsulfanyl)-2-nitroaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | Butyl bromide | HCID 8002 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | Thiocyanic acid, 4-(acetylamino)-3-nitrophenyl ester | HCID 8180927 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 4-(Butylsulfanyl)-2-nitroaniline | HCID 11031561 | — |
Reaction Steps
5 G. of 1-acetamido-2-nitro-4-thiocyanatobenzene and 2.8 ml. of n-butyl bromide are added to a solution of 4.8 g. of potassium hydroxide in 70 ml. of n-butanol. The mixture is left overnight at room temperature, then diluted with water. 1-Amino-2-nitro-4-n-butylthiobenzene is isolated by extraction with chloroform.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04072696 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-f737252ea0ff46e1963a4482e07c93b6 |
| Source note | uspto-grants-1978_02 |