HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonyl azide → 2-Diazonio-1-methoxy-7-methyl-3-oxoocta-1,6-dien-1-olate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonyl azide | HCID 13661 | — |
| Reactant | 6-Octenoic acid, 7-methyl-3-oxo-, methyl ester | HCID 10910216 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 2-Diazonio-1-methoxy-7-methyl-3-oxoocta-1,6-dien-1-olate | HCID 53854024 | 90% |
Reaction Steps
In accordance with the process of Example 1, 3-oxo-7-methyl-6-octenoic acid methyl ester (0.54 g; 2.93 m mol), triethylamine (0.30 g; 2.93 m mol) and p-toluenesulfonyl azide (0.61 g; 2.93 m mol) were used as starting materials to obtain 0.55 g of 2-diazo-3-oxo-7-methyl-6-octenoic acid methyl ester as yellow oily product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04073799 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-a9b9676530314a64988a3999275bda79 |
| Source note | uspto-grants-1978_02 |