HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonyl azide → 5-(Benzyloxy)-2-diazonio-1-methoxy-3-oxohepta-1,6-dien-1-olate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonyl azide | HCID 13661 | — |
| Reactant | Methyl 5-(benzyloxy)-3-oxohept-6-enoate | HCID 54138168 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 5-(Benzyloxy)-2-diazonio-1-methoxy-3-oxohepta-1,6-dien-1-olate | HCID 54039895 | 98.6% |
Reaction Steps
In accordance with the process of Example 2, 5-benzyloxy-3-oxo-6-heptenoic acid methyl ester (1.07 g; 4.1 m mol), p-toluenesulfonyl azide (810 mg; 4.1 m mol) and triethylamine (450 mg; 4.5 m mol) were used as starting materials to obtain 1.16 g of 5-benzyloxy-2-diazo-3-oxo-6-heptenoic acid methyl ester as yellow oily product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04073799 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-e921307e485947c2a21e6fa3b60e9b21 |
| Source note | uspto-grants-1978_02 |