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2-Chloroethyldiisopropylammonium chloride → 1-n-Propoxy-2-(2'-diisopropylaminoethoxy)-benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Chloroethyldiisopropylammonium chloride | HCID 77942 | — |
| 反応物 | o-Propoxyphenol | HCID 80476 | — |
| 反応物 | Sodium | HCID 5360545 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 1-n-Propoxy-2-(2'-diisopropylaminoethoxy)-benzene | HCID 54237134 | — |
反応手順
The compound was prepared as described in Example 1, using sodium (3.45 g; 150 mole), 0-propoxyphenol (11.4 g; 75 mmole) and diisopropylaminoethylchloride hydrochloride (15.0 g; 75 mmole) in 200 ml of ethanol. Yield 12.7 g (64%) of product, boiling at 109°-110° C under a pressure of 0.001 mm.Hg, nD25 : 1.4961. Calcd. for C17H29NO2 : C 73.07%, H 10.46%, N 5.01%. Found C 73.2% H 10.5%, N 4.96%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04073917 |
| 出典データセット | uspto-grants-1978_02 |
| ORD ID | ord-9e3be3fd5f284445a04496fd16570d20 |
| 出典メモ | uspto-grants-1978_02 |