Toluene → HCID 86735486, compound

HRID 616713Notes

Reaction equation

HRID 616713 reaction equation
[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH2:7]([Sn+:11]([CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH2:9][CH3:10].[C:20]1([CH3:26])[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>>[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH2:16]([Sn+:11]([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:17][CH2:18][CH3:19].[CH2:1]=[CH:26][C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1

Participants

3

Reactant 2

HCID 1140Toluene2×HCID 219463442155-70-6

Product 1

HCID 86735486HCID 86735486, compound

Procedure

S8 was prepared with the same additives as in S7. In this synthesis unequal molar quantities of tri-n-butyltin methacrylate (0.1 mole) and stryene (0.2 mole) were reacted with the azo initiator in 200 ml of toluene for 24 hours. The resultant polymer was a transparent, yellow tinted elastomer that could be cast as a film from the toluene solution. Analysis showed 20.46% Sn.

Workup

  1. customS8 was prepared with the same additives as in S7

Sources & evidence

ORD record
ord-183f1c64cea94fdb8b049808ee3e6f04
Source dataset
uspto-grants-1978_02
Patent number
US04075319

Reaction notes

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