3,5-Dinitrobenzoyl chloride → HCID 86735498, compound

HRID 616804Notes

Reaction equation

HRID 616804 reaction equation
[CH:1]([N:3]1[C:15]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[C:9]2[C:4]1=[CH:5][CH:6]=[CH:7][CH:8]=2)=[CH2:2].[CH:16]([OH:18])=[CH2:17].[N+:19]([C:22]1[CH:23]=[C:24]([CH:28]=[C:29]([N+:31]([O-:33])=[O:32])[CH:30]=1)[C:25](Cl)=[O:26])([O-:21])=[O:20]>N1C=CC=CC=1.C1C=CC=CC=1>[CH:1]([N:3]1[C:15]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[C:9]2[C:4]1=[CH:5][CH:6]=[CH:7][CH:8]=2)=[CH2:2].[N+:19]([C:22]1[CH:23]=[C:24]([CH:28]=[C:29]([N+:31]([O-:33])=[O:32])[CH:30]=1)[C:25]([O:18][CH:16]=[CH2:17])=[O:26])([O-:21])=[O:20]

Participants

5

Reactant 2

HCID 74323,5-Dinitrobenzoyl chlorideHCID 86735496HCID 86735496, compound

Product 1

HCID 86735498HCID 86735498, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 1049PyridineSolvent2×

Procedure

Copoly(N-vinyl carbazole-Vinyl alcohol) (II) (2.0 g) was dissolved in 50 ml of anhydrous pyridine. 3,5-Dinitrobenzoyl chloride (3.88 g) in 15 ml of anhydrous benzene was added with stirring to the pyridine solution. The resulting orange solution was stirred at room temperature for 4 hours. The small amount of solid remaining in the reaction mixture was collected on a filter and the filtrate was poured into 400 ml of methanol. The isolated polymer was purified by two precipitations from tetrahydrofuran into methanol to give 3.2 grams of a yellow powder. Nitrogen analysis demonstrated that the reaction of the alcohol groups with the acid chloride was nearly quantitative.

Workup

  1. customwas collected on
  2. filtrationa filter
  3. additionthe filtrate was poured into 400 ml of methanol
  4. customThe isolated polymer was purified by two precipitations from tetrahydrofuran into methanol

Sources & evidence

ORD record
ord-5f77568f7cc749cf891e9588f092aceb
Source dataset
uspto-grants-1978_02
Patent number
US04076526

Reaction notes

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