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HRID616856

反应详情

EQUATION

反应方程式

HRID 616856 的结构方程式

REACTANTS

反应物

3
结构：N
HCID222

Ammonia gas

H3N

结构：O=C1c2cccc([N+](=O)[O-])c2C(=O)c2cccc([N+](=O)[O-])c21
HCID6705

9,10-Anthracenedione, 1,5-dinitro-

C14H6N2O6

结构：[Br-].[NH4+]
HCID25514

未命名化合物

PRODUCTS

生成物

1
结构：Nc1cccc2c1C(=O)c1cccc([N+](=O)[O-])c1C2=O
HCID236900

1-Amino-5-nitroanthraquinone

C14H8N2O4

收率 86.2%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：OCCOCCO
溶剂HCID8117

Diethylene glycol

C4H10O3

PROCEDURE

实验过程

17.5 liters (STP)/hour of ammonia are passed, under normal pressure, for 40 minutes into a solution of 60 g of 1,5-dinitro-anthraquinone (97% pure) and 5 g of ammonium bromide in 450 g of diethylene glycol, at 220° C, while stirring vigorously. After cooling, the product is filtered off and washed with water. After drying, 46.5 g of 80.5% pure 1-amino-5-nitroanthraquinone (71.5% of theory) are obtained. The product contains 19.0% (19.0% of theory) of 1,5-diaminoanthraquinone.

WORKUP

后处理

  1. temperatureAfter cooling
  2. filtrationthe product is filtered off
  3. washwashed with water
  4. customAfter drying