反应详情

Odor: Animalic, musk, sweet, erogenous, warm-powdery.--IR (film): ν=1735 cm-1 (νC=O), 1117/1151 cm-1 (νasO--C--C), 1254 cm-1 (νasC--C(=O)--O), 1361 cm-1 (δCH3), 1060 cm-1 (νasC--O--C).--1H-NMR (CDCl3): δ=0.92 (d, J=6.8 Hz, 3H, 14-Me), 1.29-1.56 (m, 14H, 4-H2 -9-H2, 13-H2), 1.61-1.67 (m, 3-H2, 15-Hb), 1.79 (ddt, 14.0, 8.4 and 5.2 Hz, 1H, 15-Ha), 1.87 (mc, 1H, 14-H), 2.33 (dd, J=6.8 and 6.0 Hz, 2H, 2-H), 3.34-3.50 (m, 4H, 10-,12-H2), 4.15 (ddd J=11.2, 6.0 and 5.2 Hz, 1H, 16-Hb), 4.18 (ddd, J=11.2, 8.4 and 4.4 Hz, 1H, 16Ha). --13C-NMR (CDCl3): δ=18.54 (q, 14-Me), 24.80/26.15 (t, C-3,-8), 26.17 (d, C-14), 27.31/27.66/27.791/28.22 (t, C-4-C-7), 29.15 (t, C-9), 34.02 (t, C-2), 35.57 (t, C-15), 37.00 (t, C-13), 62.14 (t, C-16), 68.05/70.77 (t, C-10,-12), 174.14 (s, C-1). --MS (EI): m/z (%)=55 (100) [C4H7⊕ ], 83 (71) [C6H11⊕ ], 99 (33) [C6H11O⊕ ]113 (13) [M⊕ --C10H21O]153 (15) [M⊕ --C6H13O2 ], 169 (16) [M⊕ --C6H13O]171 (9) [C10H19O2⊕ ], 227 (1) [M⊕ --C2H3O], 241 (2) [M⊕ --CHO], 270 (1) [M⊕].--C16H30O3 (270.41): calculated C 71.07, H 11.18; found C 71.37, H 11.13.