Benzoyl chloride, 3,4,5-trimethoxy- → HCID 21850146, compound

HRID 618120Notes

Reaction equation

HRID 618120 reaction equation
[NH:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[C:3](/[CH:10]=[CH:11]/[C:12]([C:14]2[CH:19]=[C:18]([O:20][CH3:21])[C:17]([O:22][CH3:23])=[C:16]([O:24][CH3:25])[CH:15]=2)=[O:13])=[CH:2]1.[CH3:26][O:27][C:28]1[CH:29]=[C:30]([CH:34]=[C:35]([O:39][CH3:40])[C:36]=1[O:37][CH3:38])[C:31](Cl)=[O:32]>>[CH3:40][O:39][C:35]1[CH:34]=[C:30]([CH:29]=[C:28]([O:27][CH3:26])[C:36]=1[O:37][CH3:38])[C:31]([N:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[C:3](/[CH:10]=[CH:11]/[C:12]([C:14]2[CH:19]=[C:18]([O:20][CH3:21])[C:17]([O:22][CH3:23])=[C:16]([O:24][CH3:25])[CH:15]=2)=[O:13])=[CH:2]1)=[O:32]

Participants

3

Reactant 2

HCID 78282Benzoyl chloride, 3,4,5-trimethoxy-HCID 9927763170488-48-9

Product 1

HCID 21850146HCID 21850146, compound

Procedure

Substantially the same procedure as in Example 3 was repeated using Compound 1 (1.69 g) obtained in Example 1 and 3,4,5-trimethoxybenzoyl chloride (2.31 g) except that the obtained crude crystals were recrystallized from a mixed solvent of ethanol and acetone, to give Compound 59 (1.22)

Workup

  1. customobtained crude crystals
  2. customwere recrystallized from a mixed solvent of ethanol and acetone

Sources & evidence

ORD record
ord-867e085be9d74858809895fe9026eafb
Source dataset
uspto-grants-1999_09
Patent number
US05952355

Reaction notes

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